Special Collection (Printed Books)
- Work of St. Augustine (S. Augustini Opera) printed in 1555 in Paris Consist of 10 Volumes.
- Biblia Poliglotta 1657-1669 in 9 Volumes,
- The Copy of first Syro-Malabar Missal printed in 1774 in Rome and used by Fr Thomas Porukara and St. Kuriakose Elias Chavara,
- Latin Missal printed in Rome in 1884 are some of the vital records and documents.
- Complete works of saint Ephraem of Syria : Collected works,3rd volume,Printed in Rome 1743. St Ephraem lived in Fourth century and was a syriac scholar. The book was published on the life span of Pope Benedict X IV in Latin and Syriac
- Bibliotheca orientalis Clementino - Vaticana :Scriptoribus syris orthodoxis , printed in Rome 1759.
- Commentaria New litteralis by Calmet, Augustino, Printed in Venetiis in 1767
- First printed copies of Aatmanuthapam (1871) and Njanapeeusham composed by St. Kuriakose Elias Chavara.
- Printed copy of first bible translated by Manikathanar with detailed explanations.